Vectorial On‐Surface Synthesis of Polar 2D Polymer Crystals

Hydrodynamics of polar liquid crystals.

Starting from a microscopic definition of an alignment vector proportional to the polarization, we discuss the hydrodynamics of polar liquid crystals with local C infinity v symmetry. The free energy for polar liquid crystals differs from that of nematic liquid crystals (D infinity h) in that it contains terms violating the n --> -n symmetry. First we show that these Z2-odd terms induce a gener...

2D quasiperiodic plasmonic crystals

Nanophotonic structures with irregular symmetry, such as quasiperiodic plasmonic crystals, have gained an increasing amount of attention, in particular as potential candidates to enhance the absorption of solar cells in an angular insensitive fashion. To examine the photonic bandstructure of such systems that determines their optical properties, it is necessary to measure and model normal and o...

Liquid Crystals Made of Highly Polar Compounds

Macroscopic dynamics of polar nematic liquid crystals.

We present the macroscopic equations for polar nematic liquid crystals. We consider the case where one has both, the usual nematic director, n[over ] , characterizing quadrupolar order as well as the macroscopic polarization, P , representing polar order, but where their directions coincide and are rigidly coupled. In this case one has to choose P as the independent macroscopic variable. Such e...

Rhodopsin photoproducts in 2D crystals.

The published electron microscope and X-ray structures of rhodopsin have made available a detailed picture of the inactive dark state of rhodopsin. Yet, the photointermediates of rhodopsin that ultimately lead to the activated receptor species still await a similar analysis. Such an analysis first requires the generation and characterization of the photoproducts that can be obtained in crystals...